Threshold Frequency & Wavelength
Threshold frequency and threshold wavelength mark the boundary at which one photon has exactly enough energy to release an electron.
Threshold frequency and wavelength mark the boundary
Imagine increasing the radiation frequency from a low value. At first, no electrons escape. At one boundary frequency, emission just begins.
Definition
1 markWhat is meant by the threshold frequency?
Model answer: The threshold frequency is the minimum frequency of electromagnetic radiation that causes electrons to be emitted from the surface of a metal.
Definition
1 markWhat is meant by the threshold wavelength?
Model answer: The threshold wavelength is the maximum wavelength of electromagnetic radiation that causes electrons to be emitted from the surface of a metal.
At the threshold, the fastest emitted electron has zero kinetic energy. The entire photon energy is used to escape.
Symbols
- = work function of the metal (J)
- = threshold frequency for the metal (Hz)
- = Planck constant (J s)
The threshold frequency has a corresponding threshold wavelength. Using the wave equation gives the wavelength form below.
Symbols
- = threshold wavelength for the metal (m)
- = Planck constant (J s)
- = wave speed in a vacuum (m s⁻¹)
- = work function of the metal (J)
Worked example
Find the largest threshold wavelength
Potassium has a work function of 2.26 eV. Calculate its threshold wavelength (9702/42/F/M/24 Q7(c)).
- Convert the work function to joules.
- At the threshold, set the photon energy equal to the work function.
Metal B has a larger work function than metal A. Compare the threshold frequency and threshold wavelength of B with those of A. [2]
Show worked answer
B has a higher threshold frequency because more photon energy is needed. Its threshold wavelength is therefore shorter.
A larger work function needs a higher threshold frequency and gives a shorter threshold wavelength.
