Electron Diffraction
Electron diffraction is the experimental evidence that moving particles can show wave behaviour. Read the apparatus from source to screen.
Electron diffraction is the evidence for matter waves

- 1 · Electron gunA potential difference accelerates electrons into a narrow beam.
- 2 · Thin graphiteRegular atomic spacing diffracts the electron waves.
- 3 · Phosphor screenIndividual impacts build a pattern of concentric rings.
Electrons are accelerated through a potential difference and pass through thin polycrystalline graphite. The regular atomic spacing acts like a diffraction grating. Concentric rings form on the phosphor screen.
Each electron reaches one point on the screen, showing particle detection. Many electron impacts build a diffraction pattern, showing wave behaviour (9702/41/M/J/23 Q7(b)).
Key idea
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- A larger accelerating potential difference gives the electrons more kinetic energy.
- The electron momentum increases.
- The de Broglie wavelength decreases.
- The diffraction angle decreases, so the rings move closer together.
The graphite spacing has not changed. The pattern changes because the electron momentum and wavelength change.
Connect accelerating p.d. directly to momentum
For an electron accelerated from rest, the electrical energy transferred becomes kinetic energy. The relation below assumes that the electron remains non-relativistic.
Symbols
- = magnitude of the electron charge (C)
- = accelerating potential difference (V)
- = electron momentum (N s)
- = electron mass (kg)
Momentum is proportional to the square root of the accelerating potential difference, so the de Broglie wavelength is inversely proportional to that square root.
Common mistake
Explain why increasing the accelerating potential difference makes the electron-diffraction rings move closer together.
Show worked answer
The electrons gain more kinetic energy, so their momentum increases and their de Broglie wavelength decreases. For the same graphite spacing, the diffraction angle is smaller, so the rings are closer.
Electron diffraction is the required evidence: individual electron impacts form a wave-like diffraction pattern.
